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Since the replacement of Gly with basic d-Arg in position 6 caused the local anaphylactoid reaction, new analogs with neutral d-ureidoalkyl amino acids, such as d-citruline at position 6were synthesized by our group 20

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Oxidative stress, disturbed calcium homeostasis, and metabolic stress lead to the accumulation of misfolded proteins, triggering UPRER, while ROS and Ca 2+ signaling from damaged mitochondria exacerbate this burden